Private

FS 3.143

Atmospheric Composition

Details

  • Full Title

    FS 3.143: Atmospheric Processes and Composition in Complex Environments
  • Scheduled

    Talks:
    2025-09-17, 10:00 - 12:00 (LT), SOWI – HS 2
  • Convener

  • Co-Conveners

  • Assigned to Synthesis Workshop

    ---
  • Thematic Focus

    Atmosphere, Ecosystems
  • Keywords

    carbon dixoide, gases, aerosols, air pollution, climate forcers

Description

This session welcomes contributions related to chemical and compositional processes in the atmosphere relevant to complex environments including mountainous areas. While the physical modification by orography has been largely acknowledged, the status of atmospheric composition is much less understood. Atmospheric chemistry in mountainous regions is made complex by the interplay between dynamical effects and a diverse precursor mix of ozone and aerosol-forming compounds. Early modelling attempts found an underestimation of tropospheric ozone (e.g. ALPNAP) in the greater Alpine region. Another interesting aspect relates to aerosol formation processes, that have been observed to be amplified in the presence of complex topography. From a remote sensing point of view, only now atmospheric composition starts being resolved at spatial scales that can capture individual valleys (e.g. CAMS, COPERNICUS). Past shortcomings in remote sensing observations of the atmosphere over mountains therefore need to be urgently addressed by taking advantage of new high resolution models and a wide array of in-situ observations. From a chemical point of view, complex does not necessarily only relate to topography, but also to situations where highly heterogenous and complex surface emissions impact the chemistry of the atmosphere. We therefore would like to solicitate observational (remote sensing and in-situ) and modelling contributions from all aspects where complexity plays a role, this certainly includes regions impacted by mountains, but should not exclude regions where complexity is defined in a different context.

Session Settings

Individual timing request

The standard duration for oral presentations is 8 minutes for the talk and 2 minutes for discussion. If you wish to request a different timing for your session, you can submit a request to the organizers here. The presentation length must be between 7 and 12 minutes, and the discussion time must be between 2 and 4 minutes. Final approval will depend on the overall schedule and the number of registered presentations.

Select your preferred presentation length for each presenter

Select your preferred discussion length for each presenter

If you want a general introduction slot, set to "Yes"

Select here you preferred length of your introduction

min
min

Registered Abstracts

ID: 3.11542

Ultrafine particles in Innsbruck – a case study at the Innsbruck Atmospheric Observatory (IAO) in fall 2023

Lukas Fitsch
Nickus, Ulrike; Stichaner, Michael; Lamprecht, Christian; Karl, Thomas

Abstract/Description

Particulate matter (PM) is among the pollutants with the strongest evidence for public health concern, in particular the exposure to ultrafine particles (UFP) with diameters of less than 0.1µm has a high risk of adverse health effects and premature mortality. UFP may occur in high number concentrations. In the urban atmosphere, UFP originate both from combustion processes like road traffic and from the nucleation of precursor gases like oxidized VOCs of anthropogenic and natural origin. In fall 2023, particles in the size range of 10 to 1000 nm were measured with a Scanning Mobility Particle Sizer (SMPS) and were supplemented by UFP high-frequency measurements with a Partector-2 instrument (Naneos). Here, we present results on the concentration and distribution of UFP, their potential sources and on new particle formation.

ID: 3.12413

Aerosol Profiles with Pandora Sky Measurements

Marie Stöckhardt
Proietti Pelliccia, Giorgia; Momoi, Masahiro; Herreras-Giralda, Marcos; Lopatin, Anton; Torres, Benjamin; Cede, Alexander; Lind, Elena; Dubovik, Oleg; Kreuter, Axel

Abstract/Description

Influencing the radiation budget of the atmosphere and air quality, aerosol particles are crucial in climate change research and public health. Aerosols can have a wide range of optical and microphysical properties with high temporal and spatial variability, which poses a challenge in comprehensively characterizing them. The aerosol vertical distribution is relevant for several reasons: as a priori information for satellite retrievals, for constraining the impact on radiative processes and cloud formation and for particle concentration at the surface.
Lidar instruments are well established tools for retrieving aerosol profiles. Passive ground-based remote sensing measurements also provide information on aerosol profiles, but there is no established retrieval method yet. With their highest sensitivity being at low altitudes, they could complement the lidar method, which is limited to altitudes above 500m to 1000m. The Pandora spectrometer system and the Cimel photometer routinely perform direct sun and sky measurements within the Pandonia Global Network (PGN) and the Aerosol Robotic Network (AERONET). Trace gas profiles of NO2, HCHO and H20 are already retrieved based on so-called Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations, i.e. spectral sky radiance measurements at various elevation angles (at a constant azimuth angle) and applying a spectral fitting method.
Aerosol profiles are more complex to retrieve because their impact on sky radiance has no spectral signature and depends on their optical properties, which may vary widely between different types.
Here we report on first results of aerosol profile retrievals from passive ground-based remote sensing for Innsbruck, Austria. In this study we analyse two approaches. First, we use a parametrized approach based on relative sky radiance and retrieved absolute slant column densities of the oxygen dimer (O2O2) from Pandora. AOD per layer is calculated based on the comparison with look-up tables of a pure Rayleigh atmosphere and scaled by total AOD. This approach would facilitate the integration as near-real-time PGN product.
Second, we apply the optimal estimation technique of a modified version of the GRASP algorithm, fitting the measurements of sky radiance from the AERONET and slant columns from the PGN to a radiative transfer model.

ID: 3.12438

Seasonal variability of aerosol properties at Testa Grigia Observatory (3480 m), in the western Italian Alps

Stefania Gilardoni
Bonasoni, Paolo; Marinoni, Angela; Gencarelli, Christian; Diemoz, Henri; Bellini, Annachiara; Mariani, Eros; Provenzale, Antonello; Mazari, Luigi; Petracchini, Francesco

Abstract/Description

Observations of atmospheric aerosols at high elevations play a crucial role in monitoring changes in atmospheric background composition, evaluating the effects of both anthropogenic and natural aerosols at a regional scale, and enhancing our understanding of aerosol-cloud interaction mechanisms. However, high-altitude observations are limited due to environmental and technical challenges.
We will present aerosol measurements collected at the Testa Grigia Observatory, at 3,480 m in the Italian Alps. This observatory was established in 1948 for cosmic ray measurements, and continuous monitoring of aerosol particle number size distribution (ranging from 0.25 to 35 micrometers) and aerosol absorption coefficients began in 2021.
Through multivariate statistical analysis of the variability in particle number size distribution over two-year period, we identified three distinct regimes: clean conditions, long-range dust transport episodes, and pollution transport events. Back trajectory analysis indicates that clean conditions occur when the observatory is influenced by air masses that spend most of their time in the free troposphere. Pollution transport events are characterized by an increase in particle numbers in the accumulation mode, occurring exclusively during the warm season when the boundary layer extends to higher elevations. During this regime, we observed higher particle loadings, particularly when local meteorology favors transport from the Po Valley. Dust transport episodes were noted during the spring and summer, coinciding with reanalysis provided by the CAMS (Copernicus Atmosphere Monitoring Service) models.
A better understanding of the link between aerosol microphysical properties and their sources and atmospheric transport is essential for modeling the impact of particulate matter on climate change and local weather patterns.

ID: 3.12585

Bioaerosol monitoring and research at the Sonnblick Observatory (3106 m asl)

Julia Burkart
Bucci, Silvia; Kölzer, Karen; Stohl, Andreas; Weinzierl, Bernadett; Ludewig, Elke; Bastl, Maximilian

Abstract/Description

Bioaerosols are an integral and ubiquitous component of the atmospheric aerosol. Despite this, they have received little attention in the atmospheric sciences for many years. Recently, however, interest in bioaerosols has been stimulated by growing evidence that bioaerosols are not only a health concern, but may also play an important role in cloud formation. At the same time, automated and on-line instrumentation for bioaerosol research has emerged, promising new insights into the abundance and distribution patterns of bioaerosols by providing higher time resolution and less labor-intensive measurements. In particular, measurements at a mountain station in atmospheric regions where clouds form are rare.

At the Sonnblick Observatory we have installed a SwisensPoleno Jupiter next to a traditional Hirst-type pollen trap since April 2023. The SwisensPoleno Jupiter is an online aerosol monitor that obtains scattered light, two holographic images and fluorescence signals of individual aerosol particles. Using the Hirst pollen trap, particles are collected on a sticky tape and later manually examined under a microscope to visually identify pollen and fungal spores. This data is used to validate the automatic measurements.

In this presentation we will focus our discussion on selected time periods where FLEXPART simulations indicate long-range transport of air masses, e.g. from the Saharan region. For these periods, we have taken a closer look at the fluorescence properties of the particles together with the holographic images. In a previous laboratory study, we obtained representative fluorescence signals for three classes of bioaerosol particles: pollen, fungal spores and plant debris. We use these data in combination with pollen and spore counts from the Hirst trap to characterize the selected events and to contrast and compare them with periods of stagnant conditions and stronger local influence.

ID: 3.13486

Aerosol induced Changes in Glacial and Polar Ice Melt: A Multi-Scale Analysis using Remote Sensing and Transport Modeling

Satyajit Singh Saini
Arya, Dhyan Singh

Abstract/Description

While temperature anomalies are the primary drivers of glacial and polar ice melt, aerosols play a significant yet less explored role in accelerating this process. Black carbon (BC) and secondary organic aerosols (SOAs), transported over long distances, deposit onto ice surfaces, reducing albedo and enhancing radiative forcing. This leads to increased absorption of solar radiation, triggering feedback mechanisms that further amplify regional warming. Understanding the role of aerosols in glacial melt is essential for improving climate projections and mitigation strategies. This study aims to quantify aerosol deposition and its impact on ice melt using a combination of satellite remote sensing, reanalysis datasets, and atmospheric transport modeling. MODIS Aerosol Optical Depth (AOD) data, along with MERRA-2 and ERA5 reanalysis, will provide spatial and temporal trends of aerosol presence over glaciated regions. HYSPLIT backward trajectory analysis will identify potential source regions contributing to aerosol deposition in polar and high-altitude glacier environments. To assess radiative effects, the SNICAR model (Snow, Ice, and Aerosol Radiation model) will simulate surface albedo changes due to BC and SOA accumulation, improving our understanding of aerosol-induced cryosphere feedbacks. By integrating observational datasets with transport modeling, this research aims to establish a framework for assessing the role of anthropogenic and natural aerosol sources in glacial melt. The findings will help refine climate models and contribute to targeted policy recommendations for emission controls, particularly in the areas where aerosol impacts on the cryosphere remain insufficiently constrained.

ID: 3.17208

Methane Emissions in a Mountainous Urban Setting: Insights from Eddy Covariance Measurements

Michael Stichaner
Karl, Thomas; Jud, Werner; Lamprecht, Christian; Jensen, Niels; Peron, Arianna; Graus, Martin; Manca, Giovanni

Abstract/Description

Innsbruck, an urban area nestled in a mountainous region, presents unique challenges for atmospheric research due to its complex orography. This inherent complexity complicates the accurate quantification of emission sources, particularly greenhouse gases such as methane. Recognizing the importance of methane in climate change and its associated uncertainties in alpine environments, the Innsbruck Atmospheric Observatory (IAO) at the University of Innsbruck has implemented a long-term monitoring strategy employing the eddy covariance measurement technique. As a Top-Down approach, these measurements provide direct emission estimates that complement and validate conventional Bottom-Up emission inventories, which often rely on assumptions about activity data and emission factors.
Our multi-year dataset, combining continuous observations of methane, carbon dioxide, and nitrogen oxides with campaign-based non-methane volatile organic compound (NMVOC) flux measurements, enables a detailed characterization of urban methane emissions. We identify pre-flush operations and inefficient gas furnaces as the dominant methane sources, with fluxes showing a strong correlation with ethane and a negative temperature dependence. The observed ethane-to-methane ratio (~5%) aligns with the composition of the regional gas supply.
The estimated 20-year global warming potential (GWP) of methane emissions from the residential, commercial, and public sectors could be as high as 20–30% relative to CO₂ emissions, underlining the significance of unburned methane as a climate-relevant pollutant. Our findings highlight the potential for immediate emission reductions through the transition from gas furnaces to heat pumps, offering a clear path for mitigating methane emissions in urban areas. In this regard, the study emphasizes the value of long-term flux measurements in alpine urban environments for improving regional climate models and guiding effective mitigation strategies.